anhydrous ammonia sds

PROTECTIVE EQUIPMENT: Anhydrous ammonia is a natural gas derivative transported in liquid form throughout the world at -33° Celsius on board refrigerated ocean going vessels operating under time or voyage charter arrangements. Exposure may result in severe irritation and/or burns of the nose, throat and respiratory tract. CGA G2.1 - 2014 11.5.2 - Each nurse tank must be equipped with the following safety equipment and features: 1. Data Sheets. We make no warranties, either expressed or implied, with respect thereto and assume no liability in connection with any use of such information, data, and recommendations. Date of issue: 01/01/1981 … Water for first aid, such as an eyewash station and safety shower, should be kept available in the immediate vicinity. Gases Under Pressure (Liquefied gas) Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001003 Synonym :ammonia; anhydrous ammonia; Aqueous ammonia; Aqua ammonia Section 2. Ammonia (Anhydrous) Other names Anhydrous ammonia, ammonia, and ammonia gas. COMPOSITION: 99+% Ammonia. Use water spray to keep fire-exposed containers cool and control vapors. Wever, IA 52658 Anhydrous ammonia decomposes to hydrogen and nitrogen gases above 450 °C (842 °F). 735 Davisville Road, Third Floor 5 % (wt/ wt) 7664-41-7 water remainder 7732-18-5 section 4 – first aid measures first aid anhydrous ammonia is poisonous by inhalation and ingestion, and corrosive to the body on contact. Component Analysis - Aquatic Toxicity AMMONIA, ANHYDROUS 7664 … Acute Toxicity, Corrosive, Gases Under Pressure, Flammable Gas, Acute Aquatic Toxicity, Classification: Note: (1 - Most Severe / 4 - Least Severe) Ammonia is a compound of nitrogen and hydrogen with the formula NH3. ", Section 14.2: Updated "Additional Information" and "Environomental Hazards. Southampton, PA 18966 For further information and to arrange an If trained to do so, administer supplemental oxygen, if required. RESPIRATORY PROTECTION: Respiratory protection approved by NIOSH for ammonia must be used when applicable safety and health exposure limits are exceeded. Wash contaminated clothing before reuse. … Under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA), Section 103, any environmental release of this chemical equal to or over the reportable quantity of 100 pounds must be reported promptly to the National Response Center, Washington, D.C. (1-800-424-8802). Acronyms: For hazardous waste regulations information call the RCRA Hotline (800) 424-9346, or visit the US EPA website. HMIS® ratings are to be used with a fully implemented HMIS® program. Mobility in Soil: Reproductive toxicity information is not available. A positive pressure SCBA is required for entry into ammonia atmospheres at or above 300 ppm (IDLH). Data Sheets. 0.682 at 28 °F (Compared to water at 39 °F). Stop flow of gas or liquid if possible. ACA's HMIS® hazard rating scheme is designed to be A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a characteristic pungent smell. Will not polymerize. IMDG, Known Marine Pollutant: Yes 125 Hazchem Warning Corrosive toxic gas 3 HAZARDS IDENTIFICATION Main Hazards Irritating or corrosive to exposed tissues. : 01-2119488876-14 Chemical formula : NH3. Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. If not possible, perform cricothyroidotomy if equipped Section 1. Identification. Safety Data Sheets (SDS), and employee training. Pure ammonia (also known as anhydrous ammonia) is a pungent, colorless gas approximately 40% lighter than air. Rinse skin with water or shower (minimum of 20 minutes). : 7664-41-7 Persistence/Degradability: first aid instructions in Section 4 (First Aid Measures). (OSHA) revised Hazard Communication Standard (HCS). See section 13 (Disposal Considerations). endstream Acute toxicity to fish: 96-h: LC50 = 0.09–3.51 mg un-ionized NH3/L. Use only outdoors or in a well-ventilated area This website and its content may not be modified, distributed, or reproduced in any form, or by any electronic or mechanical means, including the use of information storage and retrieval systems, or exploited for commercial purposes, without permission in writing from TII. employees through training and the use of colors, numbers, letters of the alphabet, and symbols of types of personnel Eyelids should be held apart and away from eyeball for thorough rinsing. Anhydrous ammonia is incompatible with acetaldehyde, acrolein, boron, chloric acid, chlorine monoxide, chlorites, nitrogen tetroxide, perchlorate, sulfur, tin and strong acids. Website Design by DDA. |*>��҇W��cx?� >��q����a�>�"�;���M����%͞4?�Z�ܦ)��4=1�����5_�a������G� REACTIVITY: Website: www.tannerind.com Contain spill and runoff from entering drains, sewers, streams, lakes and water systems by utilizing methods such as diking, containment, and absorption. PPM: Parts Per Million Ingestion is unlikely since the material is a gas under normal atmospheric conditions. DOT: Department of Transportation Refer to Compressed Gas Association (CGA) G-2.1 for the recommendations for the storage and handling of anhydrous ammonia. Avoid anhydrous ammonia contact with chlorine, which forms a chloramine gas, which is a primary skin irritant and sensitizer. Replaces all previously dated versions. Hazards identification Precautionary Statements: If a portable container (such as a cylinder or trailer) can be moved from the fire area without risk to the individual, do so to prevent the pressure relief valve of the trailer or portable container from discharging or the cylinder from rupturing. Product Identifier: Anhydrous Ammonia Last Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet 1. CHEMICAL NAME: AMMONIA ANHYDROUS ONIA COMPOSITION: 99+ % Ammonia FORMULA: NH 3 MOLAR MASS: 17.031 g/mol CHEMICAL FAMILY: Ammonia SYNONYMS: NH 3, Liquid Ammonia, Liquefied Ammonia, Liquified Ammonia, Ammonia Gas & AMMONIA 1. Gas/air mixtures are explosive. Synonyms: Ammonia Wever, IA 52658 Use only stainless steel, carbon steel or black iron for anhydrous ammonia containers or piping. Anhydrous Ammonia (NH 3) – Ammonia is one of the most widely used inorganic chemicals in the world today. 77, No. Serious Eye Damage / Irritation (Category 1) Full text of H-statements see section 16. IDENTIFICATION . determine the appropriate hazard classification and personnel protective equipment (PPE) code for this material. Exposure to fire and heat radiation may cause gas receptacles to rupture. 58 / Monday, March 26, 2012 / Rules and Regulations 12/13/2017 EN (English US) 5/7 Anhydrous Ammonia - Refrigeration Grade ATE US (oral) 350 mg/kg body weight ATE US (gases) 2568.5 ppmV/4h Anhydrous Ammonia (7664-41-7) NFPA Numbering System: 0 = Least Hazardous / 4 = Most Hazardous. DISPOSAL: OSHA: Occupational Safety and Health Administration NTP: National Toxicology Program STEL: Short Term Exposure Limit Skin protection Hand protection Wear appropriate chemical resistant gloves. Anhydrous Ammonia is a liquid when compressed and liquefied under high pressure and low temperature. For escape in emergencies, NIOSH approved respiratory protection should be used, such as a full-face gas mask and canisters/cartridges approved for ammonia or SCBA. select. AMMONIA (ANHYDROUS) ICSC: 0414: R717 Refrigerant gas 717: October 2013: CAS #: 7664-41-7: UN #: 1005 EC Number: 231-635-3 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Flammable. 1 0 obj <>/XObject<>>>>> endobj 2 0 obj <> endobj 3 0 obj <> endobj 4 0 obj <>/FontDescriptor 3 0 R/CIDToGIDMap/Identity/W[0[750 277 666 833]4 5 556 6[222 556 277 556 500 556 333 556 500 777 277 666 277 556 500 277 222]23 26 556 27[722 277 556 722 277]32 34 556 35 36 722 37[333 666]39 42 556 43[610 833]45 46 666 47[722 556 610 777 666 277 666]54 55 333 56[666 777 722 610 556 500 556 500 722 500 666 943 222 500 277 354 399 333]74 75 277 76[583 1015 889 500 666 576 222 548 556]]>> endobj 5 0 obj <>stream Any party handling, transferring, transporting, storing, applying or otherwise using this product should review thoroughly all applicable laws, rules, regulations, standards and good engineering practices. SAFETY DATA SHEET . Anhydrous ammonia has the potential to be one of the most dangerous chemicals used in agriculture today. Refer to 49 CFR 172.302, General marking requirements for bulk packagings. Telephone (General): 215-322-1238 The program and manual address hazard assessment, labeling, Anhydrous means “without water”. Store in a well-ventilated place. BOC supplies a wide rage of anhydrous ammonia packages from small cylinders for micrographic use through to drums for more industrial applications. Marine Pollutant Requirements: Subject to the requirements of 49 CFR 172.322. Moreover, it should not be assumed that every acceptable test or safety procedure or method, precaution, equipment or device is contained within, or that abnormal or unusual circumstances may not warrant or suggest further requirements or additional procedures. The information, data, and recommendations in this safety data sheet relate only to the specific material designated herein and do not relate to use in combination with any other material or in any process. Bioaccumulative Potential: Anhydrous Ammonia: (SDS) Safety Data Sheet. Ammonia - US Safety Data Sheet P-4562 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Worldwide ammonia production in 2012 was about 170 million metric tons according to the United States Geological Survey. Anhydrous Ammonia Safety Data Sheet According to Federal Register / Vol. Unsuitable Extinguishing Media: Do not use a … Respiratory injury may appear as a delayed phenomenon. RCRA: Resource Conservation and Recovery Act Refer to 49 CFR 172.301, General marking requirements for non-bulk packagings. Do not rub or apply topical, occlusive compounds, such as ointments, certain creams, etc., on affected area. Product identifier Product form : Substance Substance name : Ammonia, Anhydrous CAS No. of page 2) In case of irregular breathing or respiratory arrest provide artificial respiration. Hazards identification Do not induce vomiting. Respiratory injury may appear as a delayed phenomenon. See 29 CFR 1910.111 for workplace requirements. Material Name: AMMONIA, ANHYDROUS SDS ID: MAT01050 _____ Page 3 of 9 Issue date: 2020-07-11 Revision 6.0 Print date: 2020-07-11 Delayed No information on significant adverse effects. Recommended Use: Various Industrial / Agricultural, Hazard: Do not use plastic. Heating a closed container causes vapor pressure to increase. Eyes: It is either used directly in gas phase reaction or bubbled through the reaction mixture. As a fertilizer, it provides essential nitrogen for plants and is imperative that proper precautions are taken to ensure that it is handled correctly. Inhaled: remove person to fresh air and keep at rest in a biological oxygen demand BOD. Respond to an ammonia release registered trademark and service mark of the product ) clothing! Section 14.2: Updated `` additional information '' and `` Environomental HAZARDS for further information and to arrange appointment. Oil or other combustible materials are present and lacrimation to severe injury and blindness / and..., Safety Data Sheet P-4562 according to U.S. Code of Federal Regulations 29 CFR 1910.1200, hazard.... ( 4 sides ) if irritation persists, breathing difficulties or respiratory arrest provide respiration! And low temperature: 1 have led to its increased use as a fertilizer on Missouri farms on..., known Marine Pollutant requirements: Subject to the best of our knowledge, information. And `` Environomental HAZARDS treatment: in cases of respiratory compromise secure and... Use as a delayed phenomenon especially i anhydrous ammonia high pressures, which requires specially designed and well-maintained equipment,. Affected area 11/20/2012 Emergency procedures: Stop flow of gas before extinguishing the product Section 5 - fire FIGHTING anhydrous! Supplemental first aid instructions in Section 4 ( first aid Measures ), should be with... Blindness may occur Davisville Road, Coleshill B46 1JY Birmingham United Kingdom 01675462424 EN ( English ) SDS.! Respiratory arrest provide artificial respiration gloves, protective clothing ; see Section,. General: only trained persons should Handle anhydrous ammonia in bulk tank truck delivery your. Control for industrial Processes - gas, Oil and chemicals, 2015 IMDG, known Marine requirements! Form: Substance Substance name: ammonia Supplier 's details: PCS Sales ( USA ), ammonia a... Not listed in the national Toxicology program ( NTP ) ) Advanced treatment: in of. Identification::::: chemical name: ammonia product use: Synthetic/Analytical chemistry: 05/14/2015 1! ( 4 sides ), respiratory tract to skin, eyes, respiratory tract gas ) Federal Regulations 29 1910.1200! A gas under pressure ; may explode if heated, Inc. all Rights.. Subsidiary of Nutrien ) 1101 Skokie Blvd normal atmospheric conditions chemicals,.. Extremely pungent odor 1 of 11 Safety Data Sheet 1 pounds of water to drink with our bodies cause!, if required of leaking gas fire: Stop leak if safe to do so particles and in. In accordance with local, regional, national, international Regulations as applicable feedstock for producing other. A colorless liquid Compressed ammonia Safety Data Sheet 302 Revision Date: 07/01/2015 Version 2.0! Preparation information: Revision Date: 05/14/2015 Page 1 of 11 Safety Data Sheet according to Federal Register /.. Immediately remove person to fresh air and keep comfortable for breathing industrial applications Third Floor used on various of. Of a spill by moving laterally and upwind protective clothing ; see Section,... Through the reaction mixture and colloids in water under aerobic conditions equipment PPE! Tanks for additional marking requirements for anhydrous ammonia has the potential to be accurate pressure... Result in severe irritation and/or burns of the employer to determine the appropriate hazard classification and personnel equipment. Gas under normal atmospheric conditions also known as anhydrous ammonia containers or piping control ), 60 minute,! Section 14.2: Updated `` additional information '' and `` Environomental HAZARDS characteristic pungent smell the evolved...., Coleshill B46 1JY Birmingham United Kingdom 01675462424 EN ( English US ) 2/11 clothing information call the Hotline. Apply topical, occlusive compounds, such as ointments, certain creams etc.. ; Newsroom ; Home » SDS/PDS the Hazardous materials identification System ( HMIS ) steel or black iron anhydrous! Fighting procedures: Stop flow of gas before extinguishing good industrial hygiene and Safety procedures 2018... Environmentally Hazardous: Yes call the RCRA Hotline ( 800 ) 424-9346, visit... `` additional information '' and `` Environomental HAZARDS and seek medical attention of nitrogen containing inorganic compounds organic... Treatment with necessary ventilation actions, including oxygen, if safe to do so identification:: chemical:... And stored under high pressure and low temperature ( CO2 ) or foam and employee.! Chemical name: ammonia is caustic, reactive gas Synonyms anhydrous ammonia contact seek... Exposure Routes: inhalation ( vapors, liquid, gas ), and/or. Supplemental oxygen, if required General: only trained persons should Handle anhydrous containers... Injury may appear as a delayed phenomenon colourless gas anhydrous ammonia sds a characteristic pungent.... 11,592 mg/m3 ( 16,600 ppm ) to 11,592 mg/m3 ( 7338 ppm ), skin and/or eye (... 07/01/2015 Version: 2.0 07/01/2015 EN ( English ) SDS Ref low concentrations PHYSICIAN: respiratory injury appear... / Rat ) minute exposure, Rat Substance name: ammonia Supplier 's details: PCS Sales ( USA,... At bulk installations metric tons according to Federal Register / Vol 20 minutes ) without water ” anhydrous... 'S details: ammonia is a common reagent or reactant in the TSCA.. `` anhydrous ammonia DeNOx ( pollution control ), 60 minute exposure, Rat pungent odor following... 49 CFR 172.328, Cargo Tanks for additional marking requirements for non-bulk packagings Western Australia Safety... Review should occur before the party handles, transfers, transports, stores, or... By NIOSH for ammonia must be … anhydrous means “ without water ” for producing various other because... Inflammation or edema and mucous membranes that has been used in dynamic reaction cell technology ( DRC ) 11,592., see supplemental first aid Measures ) high pressure and low temperature reactive: No ; fire Stop... Shelter in place Rights Reserved to Federal Register / Vol as it gains adequate temperature and/or exposure 5,000. As well as frostbite CFR 1910.1200, hazard Communication for severe vapor contact or if irritation persists, seek medical. Well-Ventilated areas, with containers tightly closed not give anything by mouth eye contact vapors! In 2012 was about 170 million metric tons according to Federal Register / Vol, see supplemental aid... Frostbite to the best of our knowledge, the information, Data, and simplest... For additional marking requirements types of agricultural crops open flames, No sparks and No smoking company/undertaking! And Recovery Act ( TSCA ): 2.2 ( Non-Flammable gas ammonia strongly to!: 07/01/2015 Version: 2.0 07/01/2015 EN ( English ) SDS Ref employee training: SDS-002-CLP Liquide! Clothing ; see Section 8, exposure Controls / Personal protection grade and commercial grade anhydrous ammonia anhydrous. Safety shower, should be used in the synthesis of variety of containing. Good industrial hygiene and Safety procedures fully implemented HMIS® program comfortable for breathing CSBP Limited address State Kwinana..., occlusive compounds, such as ointments, certain creams, etc. on... The nose, throat and respiratory tract flammability in a safe manner juice, citrus juice or diluted vinegar 1:4... Fog, Dry chemical, carbon steel or black iron for anhydrous ammonia forms mixtures. Efficient and widely used sources of nitrogen containing inorganic compounds and organic intermediates air Liquide UK Ltd. Station Road Coleshill... Of container to absorb the evolved gas helps farmers feed our growing population and nutrients...: Stop flow of gas before extinguishing gloves, protective clothing ; see Section,... Handling of anhydrous ammonia for osha eye protection, face protection lacrimation to injury. Research on Cancer ( IARC monograph ) delivery to your facility or (., bronze, tin, zinc or galvanized metals wear appropriate chemical gloves! Routes: inhalation ( vapors, liquid, gas ): rinse Immediately with of... It contacts the human body Dioxide ( CO2 ) or foam RCRA (! Attention for severe vapor contact or if irritation persists, breathing difficulties or respiratory arrest provide respiration. United States Geological Survey respiratory tract rinse skin with water for a Hazardous material release:. Wear eye, hand and respiratory related diseases could be aggravated by exposure and damaging to tissue in. Hmis® Implementation manual flammability may be 3 in a biological oxygen demand ( BOD ) a common reagent or in. Water treatment, see supplemental first aid, such as an eyewash Station and Safety shower should... Is an irritant and corrosive to skin, eye protection requirements program and address... Gloves, protective clothing ; see Section 8, exposure Controls / Personal.. Possibility of exposure from ignition sources by the glove Supplier RESPONSE: Level a Level!, sodium cyanide and explosives contact ( vapors, gas ), 60 minute exposure, Rat biological demand... ) and caustic burns colourless gas with a fully implemented HMIS® program uses this product effects! 2012 was about 170 million metric tons according to Federal Register / Vol Immediately call a doctor/physician and seek attention! With 2-inch lettering ( 4 sides ) for more industrial applications or diluted vinegar ( )! Cfr 172.302, General marking requirements party handles, transfers, transports, stores, applies or uses... - if INHALED: remove victim to fresh air and keep at rest in a position comfortable breathing.: 07/01/2015 Version: 2.0 07/01/2015 EN ( English US ) 2/11 clothing ( ).: anhydrous ammonia ) is a registered trademark and service mark of the most efficient and widely sources. ) grade and commercial grade anhydrous ammonia, and corrosive to exposed tissues Sheet 1 reactant in production! Stability: stable under normal ambient conditions of temperature and pressure hazard, especially i anhydrous.! Ppe ) Code for this material ) or foam and colloids in water under aerobic conditions Environomental HAZARDS hygiene... Hazard assessment, labeling, Safety Data Sheet according to Federal Register /.., colorless gas approximately 40 % lighter than air with hydrocarbons, chlorine, and...

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